frequency, cm–1 |
bond |
functional group |
3640–3610 (s, sh) |
O–H stretch, free hydroxyl |
alcohols, phenols |
3500–3200 (s,b) |
O–H stretch, H–bonded |
alcohols, phenols |
3400–3250 (m) |
N–H stretch |
primary, secondary amines, amides |
3300–2500 (m) |
O–H stretch |
carboxylic acids |
3330–3270 (n, s) |
–C(triple bond)C–H: C–H stretch |
alkynes (terminal) |
3100–3000 (s) |
C–H stretch |
aromatics |
3100–3000 (m) |
=C–H stretch |
alkenes |
3000–2850 (m) |
C–H stretch |
alkanes |
2830–2695 (m) |
H–C=O: C–H stretch |
aldehydes |
2260–2210 (v) |
C(triple bond)N stretch |
nitriles |
2260–2100 (w) |
–C(triple bond)C– stretch |
alkynes |
1760–1665 (s |
C=O stretch |
carbonyls (general) |
1760–1690 (s) |
C=O stretch |
carboxylic acids |
1750–1735 (s) |
C=O stretch |
esters, saturated aliphatic |
1740–1720 (s) |
C=O stretch |
aldehydes, saturated aliphatic |
1730–1715 (s) |
C=O stretch |
alpha,beta–unsaturated esters |
1715 (s) |
C=O stretch |
ketones, saturated aliphatic |
1710–1665 (s) |
C=O stretch |
alpha,beta–unsaturated aldehydes, ketones |
1680–1640 (m) |
–C=C– stretch |
alkenes |
1650–1580 (m) |
N–H bend |
primary amines |
1600–1585 (m) |
C–C stretch (in–ring) |
aromatics |
1550–1475 (s) |
N–O asymmetric stretch |
nitro compounds |
1500–1400 (m) |
C–C stretch (in–ring) |
aromatics |
1470–1450 (m) |
C–H bend |
alkanes |
1370–1350 (m) |
C–H rock |
alkanes |
1360–1290 (m) |
N–O symmetric stretch |
nitro compounds |
1335–1250 (s) |
C–N stretch |
aromatic amines |
1320–1000 (s) |
C–O stretch |
alcohols, carboxylic acids, esters, ethers |
1300–1150 (m) |
C–H wag (–CH2X) |
alkyl halides |
1300–1150 (m) |
C–H wag (–CH2X) |
alkyl halides |
1250–1020 (m) |
C–N stretch |
aliphatic amines |
1000–650 (s) |
=C–H bend |
alkenes |
950–910 (m) |
O–H bend |
carboxylic acids |
910–665 (s, b) |
N–H wag |
primary, secondary amines |
900–675 (s) |
C–H "oop" |
aromatics |
850–550 (m) |
C–Cl stretch |
alkyl halides |
725–720 (m) |
C–H rock |
alkanes |
700–610 (b, s) |
–C(triple bond)C–H: C–H bend |
alkynes |
690–515 (m) |
C–Br stretch |
alkyl halides |
m=medium, w=weak, s=strong, n=narrow, b=broad, sh=sharp
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